Tire rolling resistance, as determined by tire choice & inflation pressure, is the largest influence on mileage following vehicle design & driving style. The placarded tire pressure recommendations are designed by the OEM to provide that plush, solid feel that most buyers want, but at the expense of mileage & handling. Fill them to suit your preference, within the limits posted on the tires themselves. Also, turbodiesels must be broken-in before optimum mileage is attained, which can take quite a while (some say upwards of 60,000 miles). You can hasten this by moderately loading the engine (towing, hard acceleration) whenever you can during the break-in period. Engine treatment can also permanently determine your engine's characteristics. Extended high-rpm operation can cause cylinder glazing while excessive idling can result in glaze-like cylinder deposits, both of which are permanent detriments to efficiency, power, & emissions. Extended high-rpm operation probably isn't an issue for us in the U.S., given the 545RFE, but excessive idling may be for some. A diesel should never be idled more than it needs to be. It does no good.
This is a good article on breaking-in a diesel:
http://www.thedieselstop.com/contents/getitems.php3?Breaking%20in%20a%20Diesel%20Engine
There's also a lot of discussion on
http://tdiclub.com/
Here's a nicely comprehensive list of fuel economy tips:
http://www.ultimatesyntheticoil.com/Improve_Fuel_Economy/Increase_Fuel_Economy.htm