kdlewis1975 wrote:
Just to clarify some terminology....
Based on what I just read in the post, it seems that you guys are actually planning to distill the waste motor oil. If that is the case, you may want to consider getting a quality vacuum pump and a nitrogen tank. Put the system under vacuum and then sparge nitrogen through the distillation pot...doesn't take much, just want a gentle bubbling. This will help liberate and carry the distillate over. Use of the nitrogen also makes the process more safe since it inerts the system and helps prevent fire.
Not planning...done. And no, I don't "distill" the motor oil, because it has too few middle distillates. And no, a catalyst is not necessary for cracking, they merely lower the cracking temp, and, or target specific length chains. Nearly all my product is thermally cracked into middle length hydrocarbons of approximately 12-16 carbons(estimated by viscosity). A small amount of light and middle ends comes out through distillation as I am heating the retort up at around 200*C, but it is very negligible. The main event happens between 420*C and 480*C.
Fluidized bed catalyzers are very nice and all but way overly complicated for what I do. Besides the catalyst would be rapidly poisoned by all the metals in the oil, and the de-additiveizing process is much too expensive and complicated.
The cracked product can be further distilled once it has been cracked, but I don't go through that final polishing because the raw stream is pretty clean and my vehicles love it.
Thanks for the attempt at "clarification", but I think that I've got the science down pretty good. See more here
http://www.oiltodiesel.com/forum/index.php
Sorry to offend you. I will no longer offer clarifications. I wasn't suggesting you go out and build a fluid catalytic cracker. And really, I was just trying to be helpful.
I suspect the metals already in the oil help catalyze the process which is why you guys seem to get by with relatively low temperatures. The homolytic bond dissociation energy for a carbon-carbon bond is pretty high. I checked out the link above. It's pretty interesting stuff. You might get a lighter colored product if you perform the process under a nitrogen blanket so that there is less oxygen around...of course, having a little oxygen around my help the process. It might be interesting to submit some of your product and samples for analysis by HPLC and/or mass spec and see if corroborates the viscosity data...you could have already done this. It's just that with the temperature dependence and the fact that the viscosity-molecular weight dependence follows an exponential relationship.