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PostPosted: Mon Apr 13, 2009 11:30 am 
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BVCRD wrote:
They're "supposed" to be putting extra lubrication in the 15 ppm fuel, so that shouldn't be a problem. No such thing as too much though. Only thing I would be concerned of is the sulfer leaving sediments or clogging things, but one guy I talked to said that soot aka (graphite) was a good thing if suspended in oil. More lubrication.

Soot is abrasive according to people familiar with used engine oil analysis. Although both are made of carbon, as is diamond, soot is not graphite.

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PostPosted: Mon Apr 13, 2009 6:47 pm 
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Apparently they are indeed similar.

Titre du document / Document title
Impact of ferrocene on the structure of diesel exhaust soot as probed with wide-angle X-ray scattering and C(1s) NEXAFS spectroscopy
Auteur(s) / Author(s)
BRAUN Artur (1 2) ; HUGGINS Frank E. (1) ; KELLY Kerry E. (3) ; MUN Bongjin S. (4) ; EHRLICH Steven N. (5) ; HUFFMAN Gerald P. (1) ;
Affiliation(s) du ou des auteurs / Author(s) Affiliation(s)
(1) Department of Chemical and Materials Engineering and The Consortium for Fossil Fuel Sciences, University of Kentucky, Lexington, KY 40506, ETATS-UNIS
(2) EMPA - Swiss Federal Laboratories for Materials Testing and Research, Uberlandstrasse 129, 8600 Dübendorf, SUISSE
(3) Department of Chemical and Fuels Engineering, University of Utah, Salt Lake City, UT 84112, ETATS-UNIS
(4) Lawrence Berkeley National Laboratory, Advanced Light Source, Berkeley, CA 94720, ETATS-UNIS
(5) Brookhaven National Laboratory, National Synchrotron Light Source, Upton, NY 11973, ETATS-UNIS

Résumé / Abstract
We report on the structure of a set of diesel exhaust samples that were obtained from reference diesel fuel and diesel fuel mixed with ferrocene. Characterization was carried out with X-ray absorption spectroscopy (C(ls) NEXAFS) and wide-angle X-ray scattering (WAXS). The reference diesel soot shows a pronounced graphite-like microstructure and molecular structure, with a strong (002) graphite Bragg reflex and a strong aromatic C=C resonance at 285 eV. The mineral matter in the reference soot could be identified as Fe2O3 hematite.

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PostPosted: Mon Apr 13, 2009 8:30 pm 
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That's interesting. Do you have the rest of the paper? I'm curious to know if they measured it's lubricity, of if soot build-up in engine oil is bad because it increases the viscosity.

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PostPosted: Mon Apr 13, 2009 9:43 pm 
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UFO wrote:
That's interesting. Do you have the rest of the paper? I'm curious to know if they measured it's lubricity, of if soot build-up in engine oil is bad because it increases the viscosity.




http://cat.inist.fr/?aModele=afficheN&cpsidt=18164711

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PostPosted: Tue Apr 14, 2009 10:49 am 
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BVCRD wrote:
UFO wrote:
That's interesting. Do you have the rest of the paper? I'm curious to know if they measured it's lubricity, of if soot build-up in engine oil is bad because it increases the viscosity.




http://cat.inist.fr/?aModele=afficheN&cpsidt=18164711

Here is what I found:
Quote:
Contamination of lubricating oil by diesel soot is one of the major causes of increased engine wear, especially with most engine manufacturers opting for Exhaust Gas Recirculation (EGR) technology to curb oxides of nitrogen (NOx) emissions. The diesel soot interacts with engine oil and ultimately leads to wear of engine parts. Factors which can change or modify the characteristics of the soot surface are expected to play an important role in controlling the interactions with soot. Hence, it is important to study the interactions between soot and oil additives in order to develop high performance diesel engine oils for engines equipped with EGR.

A statistically designed experiment was developed to study the effects of soot contaminated engine oil on wear. The variables that were considered were the base stock (groups I and II), dispersant level, and zinc dithiophosphate (ZDP) level. The above three variables were formulated at two levels: low (−1) and high (1), which resulted in 23 matrix (8 oil blends). In order to study the non-linear effect of soot, it was considered as a variable and was tested at three levels: low (−1), medium (0), and high (1). This resulted in testing of 24 oil samples.

A three-body wear machine was used to simulate and estimate the extent of wear quantitatively. The extent of wear was measured as the actual loss of material, in grams. A second set of experiments were performed on a milling machine (ball-on-flat disk setup). The wear scars formed on the steel balls were examined using a scanning electron microscope (SEM) and were analyzed qualitatively to determine the effect of soot contaminated oils on wear.

The results obtained were analyzed using the general linear model (GLM) procedure of the statistical analysis system (SAS) package to determine the significance of variables on wear. The analysis indicated that wear increased nonlinearly as the amount of soot increased. Cumulative wear was more for samples with soot contamination than without soot contamination. This showed a detrimental effect of soot on the oil blends wear performance. The SAS analysis showed that the base stock and soot content were the most significant variables affecting wear. Dispersant and ZDP levels were also found to be significant. The highest wear resulted from a sample that had 4% soot.


http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6V5B-4MH8B80-3&_user=10&_rdoc=1&_fmt=&_orig=search&_sort=d&view=c&_acct=C000050221&_version=1&_urlVersion=0&_userid=10&md5=3df93aec8ddeeaf3ac59183a64ec7e87

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