Air and nitorgen expand and contract at near the same rate.
Just take the ideal gas law for example. PV=nRT
Pressure decrease proportional to temperature.
Yes, that is the ideal gas law. However, both air and nitrogen are near ideal gases any where near those pressures. Also, air is 78% nitrogen so you pretty much have all nitrogen anyways.
The compressibility factor (Z) for N2 is 0.9997 and the same for a dry air.
The compressibility factor measures how much the gas deviates from the ideal gas law. A value of 1 means no deviation. Therefore you can see both N2 and air are almost identical in thermal expansion and follow the ideal gas law very well. No notical difference in thermal expansion between air or nitrogen.
Wet air will be a slight bit different, but I am willing to bet it doesnt deviate more than 10% from the ideal gas law. If I had my handbook with me I could give you numbers on Z for damp air.
Hence, you
might be able to tell a 1 psi diffence between a N2 inflated tire and a tire inflated with very humidy air if you where lucky.
And all that is from a chemical engineering, but don't take my word on it just search around on the web and you will come to the same conclusion.
http://www.cartalk.com/content/columns/ ... er/05.html