Might want to check this out. Go to
www.penray.com , under the "Power Fleet" section, check out the Technical Bulletins, there's one labeled "Black Coolant".
From what it says, since they started using extended service ethlyene glycol based coolants several years ago, there's been quite a few reports back to the OEM's of the coolant darkening significantly in color, some to the point where it actually looked black instead of orange.
Basically, the common factor in all cases were diesel engines operated at high output or in high ambient temp conditions, using extended service ethylene glycol coolant. Other than that, there wasn't any particular type/make of diesel, brand of truck, or brand of antifreeze that could be pointed out in particular. It seemingly happens at random under the above conditions.
They analyzed the coolant, and found that it usually contained large amounts of aluminum and iron, the pH and other chemistry was way off from what it should be, and it was very corrosive.
Their recommendation was to immediately drain and flush the cooling system, and do one of the following - reduce the concentration of ethylene glycol based antifreeze to the minimum needed for operating in your particular climate, or switch to a 50/50 mix of propylene glycol based antifreeze.