Let me add a little bit more to Flash's good description!
He is correct in the fact that the cooling system on any modern vehicle cooling system will not have any pressure after it has completely cooled to ambient temperature.
If it does, there are some other issues causing the pressure!
But there is more to it; as it heats the coolant up to the normal operating temperature, the liquid will expand in volume, if there is not enough space or volume capacity in the coolant tank as this heat expansion takes place to store the heated and expanded liquid, the radiator cap will allow any excess volume to bleed over into the smaller expansion overflow tank.
Now, after the engine is shut down, the coolant temperature will rise somewhat and the volume will actually slightly increase even more as there is no water pump action to circulate the hot liquid. Although some liquid movement will continue through the radiator as long as the thermostat remains open due to natural heat convection circulation.
As the liquid (coolant) starts to cool down as it cools all the way to ambient temperature, the volume of the liquid will actually start decreasing (shrink) in size and at some point actually creates a vacuum in the coolant expansion tank which will pull or suck any excess liquid back into the system from the expansion overflow tank if there is any.
All this back and forth movement is controlled on every temperature cycle of engine startup / shutdown /cooldown by the functions of the radiator cap! So you see a well functioning radiator cap becomes very important in the total overall proper operation of a healthy coolant system!
See this thread for diagrams of coolant flows and its ancillary components on the 2.8 VM diesel engine...
viewtopic.php?f=98&t=87021 
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